Reference of 4-Cyanobenzyl bromideIn 2022 ,《Photocatalytic activity of ultrathin 2DPNs for enzymatically generating formic acid from CO2 and C-S/C-N bond formation》 appeared in Sustainable Energy & Fuels. The author of the article were Singh, Pooja; Yadav, Rajesh K.; Singh, Chandani; Chaubey, Surabhi; Singh, Satyam; Singh, Atul P.; Baeg, Jin-OoK.; Kim, Tae Wu; Gulzhian, Dzhardimalieva. The article conveys some information:
The exploration of efficient and cheap photocatalysts for the transformation of CO2 into value-added chems. is a cornerstone challenge in organic chem. Two-dimensional covalent organic frameworks (2D-COFs) have attracted a great deal of increasing demand in the field of photocatalysis. Here, we report the design and development of two-dimensional porphyrin nanoplates (2DPNs) as low-cost and highly efficient photocatalysts. The construction of 2DPNs was achieved by the reaction of 5,10,15,20-tetraphenylporphyrin (TPP) building block units via a one-pot Friedel-Crafts reaction. The study revealed that the resultant photocatalyst has many useful properties of a better catalyst such as the superb solar light-harvesting ability, suitability of the optical band-gap, and highly ordered π-electron channels facilitating efficient charge migrations. Further study provides the better utility of 2DPN photocatalysts in the generation of solar fine chems. via the formation of C-S and C-N bonds under solar light irradiation with excellent reusability property. Furthermore, the 2DPN photocatalysts have been efficiently used as catalysts in the CO2 fixation and generation of formic acid as a green energy source under metal-free conditions. The experimental part of the paper was very detailed, including the reaction process of 4-Cyanobenzyl bromide(cas: 17201-43-3Reference of 4-Cyanobenzyl bromide)
4-Cyanobenzyl bromide(cas: 17201-43-3) is an important intermediate for pharmaceutical production. It can be used for the synthesis of a series of piperidine-linked aromatic diimidazolines, which have been synthesized as conformationally restricted congeners of the anti-Pneumocystis carinii (PCP) drug, Pentamidine.Reference of 4-Cyanobenzyl bromide
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts