Park, Kyeong-Yong; Lee, Jinyong; Park, Seong Jun; Heo, Jung-Nyoung; Lim, Hwan Jung published the artcile< Regioselective Synthesis of 1,2- and 1,4-Dihydroquinolines by Palladium-Catalyzed Intramolecular N-Arylation>, Related Products of 886761-96-2, the main research area is bromoaryl enamine palladium intramol arylation catalyst; dihydroquinoline regioselective preparation.
A series of 1,2- and 1,4-dihydroquinolines has been successfully prepared The Pd-catalyzed intramol. N-arylation of Z-enamines, formally prepared by the Horner-Wadsworth-Emmons olefination, proceeded efficiently to furnish the cyclized products. Depending on the cyclization conditions, substituted 1,4-dihydroquinolines and further isomerized 1,2-dihydroquinolines were independently obtained in high yields with an excellent control of isomerization of the double bond.
Advanced Synthesis & Catalysis published new progress about Arylation (intramol.). 886761-96-2 belongs to class nitriles-buliding-blocks, and the molecular formula is C8H5BrFN, Related Products of 886761-96-2.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts