Akkoc, Mitat; Bugday, Nesrin; Altin, Serdar; Yasar, Sedat published an article in 2021. The article was titled 《Magnetite@MCM-41 nanoparticles as support material for Pd-N-heterocyclic carbene complex: A magnetically separable catalyst for Suzuki-Miyaura reaction》, and you may find the article in Applied Organometallic Chemistry.Application In Synthesis of 2-Bromobenzonitrile The information in the text is summarized as follows:
The magnetite@MCM-41@NHC@Pd catalyst was obtained with Pd metal bound to the NHC ligand anchored to the surface of Fe3O4@MCM-41. It was characterized by Fourier transform IR (FTIR) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), XPS, energy disperse X-ray anal. (EDX), thermogravimetric anal. (TGA), DTA, and SEM. The amount of Pd in the magnetite@MCM-41@NHC@Pd was measure by inductively coupled plasma-optical emission spectroscopy (ICP-OES) anal. The catalytic activity of magnetite@MCM-41@NHC@Pd heterogeneous catalyst done on Suzuki-Miyaura reactions of aryl halides with different substituted arylboronic acid derivatives All coupling reactions afforded excellent yields and up to 408404 turnover frequency (TOF) h-1 in the presence of 2 mg of magnetite@MCM-41@NHC@Pd catalyst (0.0564 mmol g-1, 0.01127 mmol% Pd) at room temperature in 2-propanol/H2O (1:2). Moreover, magnetite@MCM-41@NHC@Pd catalyst was recover by applying the magnet and reused for another reaction. The catalyst showed excellent structural and chem. stability and reused ten times without a substantial loss in its catalytic performance. The experimental process involved the reaction of 2-Bromobenzonitrile(cas: 2042-37-7Application In Synthesis of 2-Bromobenzonitrile)
2-Bromobenzonitrile(cas: 2042-37-7) is used as a starting material to synthesize novel benzothiophene derivatives that were found to exhibit antibacterial and antifungal activity. It is commonly employed in reactions that require an electron-rich species to carry out nucleophilic substitution (or addition) reactions.Application In Synthesis of 2-Bromobenzonitrile
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts