Kostromitin, Vladislav S.; Zemtsov, Artem A.; Levin, Vitalij V.; Dilman, Alexander D. published their research in Advanced Synthesis & Catalysis on December 7 ,2021. The article was titled 《Photocatalytic Atom-Transfer Radical Addition of Activated Chlorides to Alkenes》.Related Products of 1403850-00-9 The article contains the following contents:
A protocol for performing atom transfer radical addition of activated alkyl chlorides to alkenes was described. The reaction was promoted by blue light in the presence of an organic photocatalyst (3DPA2FBN), serving to generate free radicals, and a copper complex (IMesCuCl), which facilitates the chlorine transfer step. The reaction worked efficiently with fluorinated and non-fluorinated α-chloroesters. In addition to this study using 2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile, there are many other studies that have used 2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile(cas: 1403850-00-9Related Products of 1403850-00-9) was used in this study.
2,4,6-Tris(diphenylamino)-3,5-difluorobenzonitrile(cas: 1403850-00-9) is cyanoarene-based donor-acceptor photocatalyst developed by the Zeitler group. While this catalyst has a balanced redox profile, allowing for its use in a variety of transformations, it stands out as the most reducing catalyst of the family.Related Products of 1403850-00-9
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts