Recommanded Product: 2-BromobenzonitrileIn 2022 ,《Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SO2》 was published in Angewandte Chemie, International Edition. The article was written by Lou, Terry Shing-Bong; Kawamata, Yu; Ewing, Tamara; Correa-Otero, Guillermo A.; Collins, Michael R.; Baran, Phil S.. The article contains the following contents:
The sulfonyl fluorides ArSO2F [Ar = 2-MeOC6H4, 4-FC6H4, 3,5-di-MeC6H3, etc.] were synthesized via electrochem. sulfinylation and fluorination of aryl iodides and bromides through aryl sulfinate intermediate using an inexpensive Ni-electrocatalytic protocol. The reaction exhibited a broad scope, used stock solution of simple SO2 as sulfur source, and could be scaled up in batch and recycle flow settings. The limitations of this reaction were clearly shown and put into context by benchmarking with state-of-the-art Pd-based methods. The experimental process involved the reaction of 2-Bromobenzonitrile(cas: 2042-37-7Recommanded Product: 2-Bromobenzonitrile)
2-Bromobenzonitrile(cas: 2042-37-7) belongs to a group of ortho-substituted bromobenzenes that have varying hepatotoxicity effects in the presence of rat liver microsomes in vitro. 2-Bromobenzonitrile is also used as a starting material to synthesize novel benzothiophene derivatives that were found to exhibit antibacterial and antifungal activity.Recommanded Product: 2-Bromobenzonitrile
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts