Research on new synthetic routes about 166329-43-7

This compound(tert-Butyl (2-(bromomethyl)phenyl)carbamate)SDS of cas: 166329-43-7 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.

SDS of cas: 166329-43-7. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: tert-Butyl (2-(bromomethyl)phenyl)carbamate, is researched, Molecular C12H16BrNO2, CAS is 166329-43-7, about A Phosphorus(III)-Mediated (4+1)-Cycloaddition of 1,2-Dicarbonyls and Aza-o-Quinone Methides to Access 2,3-Dihydroindoles. Author is Eckert, Kaitlyn E.; Lepore, Antonio J.; Ashfeld, Brandon L..

A [4+1]-cycloaddition was reported between 1,2-dicarbonyls and aza-o-quinone methide precursors to access 2,3-dihydroindoles e.g. I bearing a tetra-substituted carbon center. The utilization of dioxyphospholenes as carbene surrogates provided dihydroindoles in 20-90% yield, wherein the electronic nature of the dioxyphospholene impacts its role in the reaction.

This compound(tert-Butyl (2-(bromomethyl)phenyl)carbamate)SDS of cas: 166329-43-7 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.

Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts