Electric Literature of C10H14MoO6. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Supramolecular frameworks formed via hydrogen bonding and non-covalent interactions and interaction energy calculations of solvent coordinated cis-dioxomolybdenum(VI) complexes derived from ONO donor aroylhydrazone: Cytotoxicity studies. Author is Kuriakose, Daly; Prathapachandra Kurup, M. R..
A tridentate ONO donor aroylhydrazone, 3,5-diiodosalicylaldehyde-4-methoxybenzoylhydrazone (H2SMB) and four cis-MoO2 complexes [MoO2(SMB)(DMF)] (1), [MoO2(SMB)(DMSO)] (2), [MoO2(SMB)(py)] (3) and [MoO2(SMB)(3-pic)] (4) which vary the solvents/heterocyclic bases in the sixth coordination position were synthesized. The compounds were characterized by different physicochem. methods. The single crystal X-ray diffraction studies unambiguously confirm the mol. structures. In the complexes 1, 2, 3 and 4, the octahedral geometry around the Mo(VI) central atom is satisfied by ONO donor atoms and two oxo oxygens, the sixth coordination site is occupied by oxygen/nitrogen atoms of solvent mols. The supramol. architectures generated by various hydrogen bonding and non-bonding interactions were studied. The interaction energy calculations reveal dominance of dispersion energy component over other components. The aroylhydrazone was screened for antioxidant study using DPPH assay. The in vitro cytotoxicity of Mo(VI) complexes was evaluated against lymphoma ascites cell line as well as against normal cell and compared to hydrazone and cyclophosphamide.
《Supramolecular frameworks formed via hydrogen bonding and non-covalent interactions and interaction energy calculations of solvent coordinated cis-dioxomolybdenum(VI) complexes derived from ONO donor aroylhydrazone: Cytotoxicity studies》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Electric Literature of C10H14MoO6.
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts