Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 484-47-9, is researched, SMILESS is C1(C2=CC=CC=C2)=NC(C3=CC=CC=C3)=C(C4=CC=CC=C4)N1, Molecular C21H16N2Journal, Article, ACS Omega called Visible Light-Emitting Diode Light-Driven Cu0.9Fe0.1@RCAC-Catalyzed Highly Selective Aerobic Oxidation of Alcohols and Oxidative Azo-Coupling of Anilines: Tandem One Pot Oxidation-Condensation to Imidazoles and Imines, Author is Patel, Ashok Raj; Patel, Geetika; Banerjee, Subhash, the main research direction is alc aerobic oxidation carbon supported copper iron photocatalytic nanocatalyst; ketone aldehyde preparation green chem; aniline oxidative azo coupling carbon supported copper iron nanocatalyst; diazo compound preparation green chem; tandem one pot oxidation condensation carbon supported copper iron; imidazoles imine preparation green chem.Safety of 2,4,5-Triphenylimidazole.
Here, we have demonstrated visible light-emitting diode light-driven selective and efficient aerobic oxidation of primary/secondary alcs. to aldehydes/ketones and oxidative azo-coupling of anilines using biomass rice husk-derived chem. activated carbon sheet-supported copper-iron bimetallic hybrid nanomaterials (CuxFe1-x@RCAC) under oxidant and additive-free conditions. The catalytic activity of the CuxFe1-x@RCAC materials has been investigated for the oxidation of alcs. and anilines, and Cu0.9Fe0.1@RCAC was established as the best catalyst. Moreover, a tandem one-pot protocol has been developed for the sequential oxidation of alcs. followed by condensation to functionalized imidazole and imine derivatives in high isolated yields. The hybrid materials were highly robust and stable under the reaction conditions and were recovered simply by filtration and recycled up to 12th run without considerable loss in catalytic activity.
《Visible Light-Emitting Diode Light-Driven Cu0.9Fe0.1@RCAC-Catalyzed Highly Selective Aerobic Oxidation of Alcohols and Oxidative Azo-Coupling of Anilines: Tandem One Pot Oxidation-Condensation to Imidazoles and Imines》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(2,4,5-Triphenylimidazole)Safety of 2,4,5-Triphenylimidazole.
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts