In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Oxovanadium and dioxomolybdenum complexes: synthesis, crystal structure, spectroscopic characterization and applications as homogeneous catalysts in sulfoxidation, published in 2021, which mentions a compound: 17524-05-9, mainly applied to Oxovanadium oxomolybdenum ethoxysalicylaldehyde nicotinic hydrazide Schiff complex catalyst preparation; crystal structure Oxovanadium oxomolybdenum ethoxysalicylaldehyde nicotinic hydrazide Schiff complex; DFT calculation Oxovanadium oxomolybdenum ethoxysalicylaldehyde nicotinic hydrazide Schiff complex; sulfoxidation catalyst Oxovanadium oxomolybdenum ethoxysalicylaldehyde nicotinic hydrazide Schiff complex, Product Details of 17524-05-9.
New oxovanadium and dioxomolybdenum Schiff base complexes, [VO(L)(OCH3)]n and [MoO2(L)(CH3OH)], were synthesized by treating an ONO donor Schiff base (H2L) derived by condensation of 3-ethoxysalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum (VO(acac)2 and MoO2(acac)2), resp. The synthesized ligand and complexes were characterized by FTIR, multinuclear (1H, 13C) NMR, elemental and single crystal x-ray diffraction anal. In both complexes, the geometry around the central metal ions was distorted octahedral as revealed by diffraction studies. Theor. calculations of the synthesized compounds were carried out by DFT at B3LYP/Def2-TZVP level of theory, which showed good correlation with the exptl. results. Also, the catalytic efficiency of both complexes was investigated by oxidizing aryl and alkyl sulfides in the presence of 30% H2O2 in ethanol.
This compound(Bis(acetylacetonato)dioxomolybdenum(VI))Product Details of 17524-05-9 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts