Jameel, Dunya A.; Hussein, Mouayed A.; Bader, Mohammed J. published an article about the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9,SMILESS:O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O ).Reference of Bis(acetylacetonato)dioxomolybdenum(VI). Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:17524-05-9) through the article.
In mole ratio 1:2, six molybdenum (VI) complexes were synthesized by the reaction of MoO2(acac)2 with semicarbazone ligands derived from 4-methylbenzaldehyde (1A and 2A), and 4-methoxybenzaldehyde (1B and 2B). The synthesized ligands and complexes were structurally characterized by CHNS elemental anal. and FTIR, 1HNMR and 13CNMR spectroscopic techniques. The DNA binding activity with all the compounds was investigated using the spectral titration method and the viscosity measurement. The results revealed the external groove binding mode of the ligands 2A, 1B and 2B, and all the complexes with DNA while, the ligand 1A showed an intercalation binding with DNA. The calculated binding constants (Kb) were extracted and the values exhibited a noticed binding strength with DNA.
《Spectroscopic elucidation and dna binding evaluation of molybdenum (VI) with 4-methyl (methoxy) benzaldehyde semicarbazone》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Reference of Bis(acetylacetonato)dioxomolybdenum(VI).
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts