Product Details of 17524-05-9. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity of novel oxovanadium and dioxomolybdenum complexes with ONO tridentate Schiff base ligand. Author is Kargar, Hadi; Bazrafshan, Maryam; Fallah-Mehrjardi, Mehdi; Behjatmanesh-Ardakani, Reza; Rudbari, Hadi Amiri; Munawar, Khurram Shahzad; Ashfaq, Muhammad; Tahir, Muhammad Nawaz.
For the first time, two new oxovanadium and dioxomolybdenum Schiff base complexes, VOL(OMe) and MoO2L, were synthesized through the reaction of a ONO tridentate Schiff base ligand (H2L) derived from the condensation of 5-bromosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)2 and MoO2(acac)2], resp. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FTIR, 1H NMR, 13C NMR, elemental anal. (CHN) and the most authentic single crystal x-ray diffraction anal. (SC-XRD). The geometry around the central metal ion in MoO2L was distorted octahedral as revealed by the data collected from diffraction studies. Noncovalent interactions that are responsible for crystal packing are explored by Hirshfeld surface anal. Theor. calculations of the synthesized compounds, carried out by DFT at B3LYP/Def2-TZVP level of theory, indicated that the calculated results are in agreement with the exptl. findings. Also, the catalytic activities of both complexes were investigated for the selective oxidation of benzylic alcs. using urea hydrogen peroxide (UHP) in acetonitrile.
Different reactions of this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Product Details of 17524-05-9 require different conditions, so the reaction conditions are very important.
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts