Synthetic Route of C10H14MoO6. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Geometrically Constrained Molybdenum(VI) Metallosupramolecular Architectures: Conventional Synthesis versus Vapor and Thermally Induced Solid-State Structural Transformations. Author is Vrdoljak, Visnja; Mandaric, Mirna; Hrenar, Tomica; Djilovic, Ivica; Pisk, Jana; Pavlovic, Gordana; Cindric, Marina; Agustin, Dominique.
This contribution describes the synthesis, characterization, and catalytic implementation of the highly constrained Mo(VI) polymers [MoO2(LR)]n (with R = H 1, 3OMe 2, and 4OMe 3) and cyclic tetramer [MoO2(L4OMe)]4·0.5MeCN (3’·0.5MeCN) with nicotinoyl hydrazonato ligands (LR) derived from salicylaldehyde (LH), 3-methoxy-2-hydroxybenaldehyde (L3OMe), or 4-methoxy-2-hydroxybenzaldehyde (L4OMe). To determine the most stable geometries, conformational anal. of the free and coordinated ligands in these assemblies was carried out through the potential energy surface scans using quantum-chem. methods. The mononuclear analogs [MoO2(HLR)(MeOH)]Cl (R = H 1a and 3OMe 2a), [MoO2(HLR)Cl] (R = 3OMe 2b and 4OMe 3b), and [MoO2(LR)(MeOH)] (R = H 1c, and 4OMe 3c-α and 3c-β) were also synthesized and evaluated as potential precursors for reactions in the solid state. Vapor induced transformation of 2a quant. afforded complex 2b. The chemometric anal. using principal component anal. was applied to provide insight into the reaction profile. Thermally induced solid-state reactions resulted in the transformation of metallocycle 3’·0.5MeCN and monomeric complexes 1c, 2a, 3c-α, and 3c-β into the corresponding coordination polymers. The structural features responsible for these conversions are discussed. Lastly, the metallosupramol. architectures were tested as catalysts for cyclooctene epoxidation by using tert-Bu hydroperoxide as an oxidant in H2O or decane. Compound 3′ is the most effective and selective catalyst.
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Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts