The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about MoS2-Stratified CdS-Cu2-xS Core-Shell Nanorods for Highly Efficient Photocatalytic Hydrogen Production, the main research direction is molybdenum cadmium copper sulfide nanorod photocatalyst hydrogen evolution reaction; water splitting molybdenum cadmium copper nanorod heterojunction photocatalyst; CuI@MoS2 catalytic and protective layers; femtosecond transient absorption; mapping surface charge distribution; photocatalytic water splitting; stratified CdS-Cu2−xS/MoS2.SDS of cas: 17524-05-9.
Heterojunction photocatalysts are widely adopted for efficient water splitting, but ion migration can seriously threaten the stability of heterojunctions, as with the well-known low stability of CdS-Cu2-xS due to intrinsic Cu+ ion migration. Here, Cu+ migration is utilized to design a stratified CdS-Cu2-xS/MoS2 photocatalyst, in which CuI@MoS2 (CuI-intercalated within the MoS2 basal plane) is created by Cu+ migration and intercalation to the adjacent MoS2 surface. The epitaxial vertical growth of the CuI@MoS2 nanosheets on the surface of one-dimensional core-shell CdS-Cu2-xS nanorods forms catalytic and protective layers to simultaneously enhance catalytic activity and stability. Charge transfer is verified by kinetics measurements with femtosecond time-resolved transient absorption spectroscopy and direct mapping of the surface charge distribution with a scanning ion conductance microscope. This design strategy demonstrates the potential of utilizing hybridized surface layers as effective catalytic and protective interfaces for photocatalytic hydrogen production
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Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts