The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis(acetylacetonato)dioxomolybdenum(VI)(SMILESS: O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O,cas:17524-05-9) is researched.COA of Formula: C6Cl2N4. The article 《Novel oxovanadium and dioxomolybdenum complexes of tridentate ONO-donor Schiff base ligand: Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity for the selective oxidation of benzylic alcohols》 in relation to this compound, is published in Inorganica Chimica Acta. Let’s take a look at the latest research on this compound (cas:17524-05-9).
Two new oxovanadium and dioxomolybdenum Schiff base complexes, [VVO(L)(OCH3)(CH3OH)] and [MoVIO2(L)(CH2CH3OH)], were synthesized by treating an ONO-donor type Schiff base ligand (H2L) derived by condensation of 5-nitrosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)2 and MoO2(acac)2], resp. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FT-IR, multinuclear (1H, 13C) NMR, elemental anal. and the most authentic single crystal X-ray diffraction anal. In both complexes the geometry around the central metal ions was distorted octahedral as revealed by the data collected from diffraction studies. Theor. calculation of the synthesized compounds were carried out by DFT as well as TD-DFT using B3LYP method by employing the Def2-TZVP basis set. The findings of theor. data indicated that the calculated results are in accordance with the exptl. findings. Moreover, the catalytic efficiencies of both complexes were investigated by oxidizing the benzylic alcs. in the presence of urea hydrogen peroxide (UHP) in acetonitrile.
From this literature《Novel oxovanadium and dioxomolybdenum complexes of tridentate ONO-donor Schiff base ligand: Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity for the selective oxidation of benzylic alcohols》,we know some information about this compound(17524-05-9)Electric Literature of C10H14MoO6, but this is not all information, there are many literatures related to this compound(17524-05-9).
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts