Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Selective oxidation of benzyl alcohols to benzaldehydes catalyzed by dioxomolybdenum Schiff base complex: synthesis, spectral characterization, crystal structure, theoretical and computational studies.Recommanded Product: Bis(acetylacetonato)dioxomolybdenum(VI).
A novel dioxomolybdenum Schiff base complex, compound I, was synthesized by treating MoO2(acac)2 with an ONO donor Schiff base ligand 4-amino-N’-(2-hydroxy-3-methoxybenzylidene)benzohydrazide derived by the condensation of 4-aminobenzohydrazide and 3-methoxysalicylaldehyde. Single-crystal X-ray anal. was also accomplished to ensure the mol. structure of the complex. The geometry around the central metal atom in compound I was distorted octahedral as revealed by the data collected from diffraction studies. Theor. calculations of the synthesized compounds were carried out by DFT at B3LYP/Def2-TZVP level of theory, which showed a good correlation with the exptl. findings. Moreover, the homogeneous catalytic efficiency of the complex was investigated by the process of selective oxidation of benzylic alcs. using urea hydrogen peroxide (UHP) in acetonitrile under reflux conditions.
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Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts