In 2019 J CHROMATOGR A published article about METAL-ORGANIC FRAMEWORKS; ABSOLUTE STRUCTURE DETERMINATION; STATIONARY PHASES; ENANTIOMER SEPARATION; RESOLUTION; RECOGNITION; HPLC; SULFOXIDES; CATALYSIS; ISOMERS in [Wang, Zi-Meng; Yang, Cheng-Xiong] Nankai Univ, Tianjin Key Lab Mol Recognit & Biosensing, Res Ctr Analyt Sci, Coll Chem, Tianjin 300071, Peoples R China; [Yan, Xiu-Ping] Jiangnan Univ, State Key Lab Food Sci & Technol, Int Joint Lab Food Safety, Inst Analyt Food Safety,Sch Food Sci & Technol, Wuxi 214122, Jiangsu, Peoples R China in 2019, Cited 51. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4. COA of Formula: C8H9N
Chiral crystalline sponges (CCSs) are a recent class of chiral porous metal complexes potential in chiral recognition. Here we report the fabrication of polysiloxane OV-1701 incorporated CCS-3S (PSO/CCS-3S) coated capillary column as a novel stationary phase for gas chromatographic separation of diverse race-mates. CCS-3S with the chiral ligand of (S)-mandelic was selected as the model CCS. With the aid of polysiloxane OV-1701, PSO/CCS-3S coated capillary column gave improved resolution, broader enantiomers separation scope and much larger McReynolds constants than CCS-3S coated capillary column. Many racemates that cannot be separated on CCS-3S coated capillary column were well resolved on PSO/CCS-3S coated capillary column. The PSO/CCS-3S coated capillary column also gave wide linear range, low limit of detection, good repeatability and reproducibility, and fine inertness and anti-column bleeding properties for the separation of enantiomers. In addition, the PSO/CCS-3S coated capillary column presented better resolution for the studied racemates than commercial beta-cyclodextrin based Cyclosil B (30 m long x0.32 mm i.d. x 0.25 mu m film thickness), beta-DEX 225 (30 m long x0.25 mm i.d. x 0.25 mu m film thickness) and amino acid based Chirasil L-Val (25 m long x0.25 mm i.d. x 0.12 mu m film thickness) capillary columns. These results indicate the great potential of PSO/CCS-3S coated capillary column in separation of enantiomers. (C) 2019 Elsevier B.V. All rights reserved.
COA of Formula: C8H9N. Bye, fridends, I hope you can learn more about C8H9N, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts