In an article, author is Xiao, Jing, once mentioned the application of 2920-38-9, Recommanded Product: [1,1′-Biphenyl]-4-carbonitrile, Name is [1,1′-Biphenyl]-4-carbonitrile, molecular formula is C13H9N, molecular weight is 179.2173, MDL number is MFCD00001821, category is nitriles-buliding-blocks. Now introduce a scientific discovery about this category.
Copper-catalyzed radical oxidative C(sp(3))-H/C(sp(3))-H cross-coupling between arylacetonitriles and benzylic compounds
For the first time, a novel copper-catalyzed direct C(sp(3))-H/C(sp(3))-H cross-coupling of arylacetonitriles with unactivated benzylic compounds was described, allowing various a-benzylated arylacetonitriles to be readily accessible under base-free conditions. Mechanistic investigations suggested that the reaction proceeds through radical process and the C(sp(3))-H cleavage of arylacetonitriles probably is the rate-determining step. (C) 2020 Elsevier Ltd. All rights reserved.
If you are interested in 2920-38-9, you can contact me at any time and look forward to more communication. Recommanded Product: [1,1′-Biphenyl]-4-carbonitrile.