In an article, author is Xia, Qing, once mentioned the application of 623-03-0, Recommanded Product: 4-Chlorobenzonitrile, Name is 4-Chlorobenzonitrile, molecular formula is C7H4ClN, molecular weight is 137.57, MDL number is MFCD00001813, category is nitriles-buliding-blocks. Now introduce a scientific discovery about this category.
Electron Donor-Acceptor Complex-Initiated Photochemical Cyanation for the Preparation of alpha-Amino Nitriles
An electron donor-acceptor complex-initiated alpha-cyanation of tertiary amines has been described. The reaction protocol provides a novel method to synthesize various alpha-amino nitriles under mild conditions. The reaction can proceed smoothly without the presence of photocatalysts and transition metal catalysts, and either oxidants are unnecessary or O-2 is the only oxidant. The practicality of this method is showcased not only by the late-stage functionalization of natural alkaloid derivatives and pharmaceutical intermediate, but also by the applicability of a stop-flow microtubing reactor.
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