In an article, author is Emmetiere, Fabien, once mentioned the application of 590-17-0, Safety of 2-Bromoacetonitrile, Name is 2-Bromoacetonitrile, molecular formula is C2H2BrN, molecular weight is 119.948, MDL number is MFCD00001884, category is nitriles-buliding-blocks. Now introduce a scientific discovery about this category.
Functional Group Interconversion of Alkylidenemalononitriles to Primary Alcohols by a Cooperative Redox Operation
Functional group interconversions are essential chemical processes enabling synthesis. In this report, we describe a strategy to convert alkylidenemalononitriles into primary alcohols in one step. The reaction relies on a choreographed redox process involving alkylidene reduction, malononitrile oxidation, and acylcyanide reduction where molecular oxygen and NaBH(4)work cooperatively. The method was applied to a variety of carbon skeletons and was utilized to synthesize complex terpenoid architectures.
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