Reference of 123-06-8, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 123-06-8, Name is Ethoxymethylenemalononitrile, SMILES is N#C/C(C#N)=C/OCC, belongs to nitriles-buliding-blocks compound. In a article, author is Middel, Christoph, introduce new discover of the category.
Rhodium-Catalyzed Regioselective 3-Fluoroallylic Cyanation
A rhodium catalyzed allylic cyanation of 3-fluoroallylic trifluoroacetates with TMSCN and a bulky phosphite ligand gives 3-fluoroallylic nitriles with a good substrate scope and high Z/E-selectivity. For dialkylated substrates the fluorine substituent controls the regioselectivity in favor of the distal product. For the stereoselectivity of the allylic cyanation selected scalemic substrates showed inversion of the stereocenter and some or no stereoerosion.
Reference of 123-06-8, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 123-06-8.