Application of 766-84-7, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 766-84-7, Name is 3-Chlorobenzonitrile, SMILES is N#CC1=CC=CC(Cl)=C1, belongs to nitriles-buliding-blocks compound. In a article, author is Tayu, Masanori, introduce new discover of the category.
A Catalytic Construction of Indoles via Formation of Ruthenium Vinylidene Species from N-Arylynamides
Treatment of ynamides with a catalytic amount of TpRuCl(PPh3)(2) resulted in the construction of indole scaffolds known as privileged structure motifs. This reaction involved a cascade of 1,2-rearrangement and cyclization carrying out C-C bond formation via a ruthenium vinylidene intermediate, as revealed by a deuterium-labeling experiments. Furthermore, the transformation of multi-functionalized ynamide, derived from a practical drug molecule, showed a high functional group tolerance of this reaction.
Application of 766-84-7, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 766-84-7.