Research on new synthetic routes about 873-74-5

According to the analysis of related databases, 873-74-5, the application of this compound in the production field has become more and more popular.

Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 873-74-5, name is 4-Aminobenzonitrile, This compound has unique chemical properties. The synthetic route is as follows., Application In Synthesis of 4-Aminobenzonitrile

General procedure: A mixture of amine 1 (0.50 mmol), 1,3-diketone 2 (0.60 mmol, 1.2 equiv), iodine(12.7 mg, 0.05 mmol, 10 mol%) and TsOHH2O (19.0 mg, 0.10 mmol, 20 mol%) in 1,4-dioxane (3 mL) was added into a Schlenk flask (25 mL) and stirred at room temperature.The mixture was stirred at 140 C until the reaction was finished. Then, the solvent wasevaporated under reduced pressure and the residue was purified by column chromatography(petroleum ether/ethyl acetate 5:1 to 2:1) to afford the product 3.

According to the analysis of related databases, 873-74-5, the application of this compound in the production field has become more and more popular.

Reference:
Article; Zhou, Xiao-Yu; Chen, Xia; Yang, Dan; Synthetic Communications; vol. 50; 2; (2020); p. 177 – 184;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts